tert-Butyl 5-methoxy-3-pentylindole-1-carboxylate

he molecule of the title compound, C₁₉H₂₇NO₃, is essentially planar, with all non-H atoms within 0.2 Å of the nine-membered indole plane, except for the three tert-butyl C atoms. The C₅ pentyl chain is in an extended conformation, with three torsion angles of 179.95 (13), 179.65 (13) and -178.95 (15)° (the latter two angles include the C atoms of the C5 chain only). Three intramolecular C-H...O=C contacts are present (C...O 115°), and an intermolecular C-H...O=C contact and π-π stacking complete the intermolecular interactions

An analysis of the duties of general clerical workers in the General Electric Company

Thesis (M.A.)--Boston University 1949. This item was digitized by the Internet Archive

Radio or newspaper advertising for retailers

This item was digitized by the Internet Archive

The archaeology of scattered wreck-sites: formation processes and shallow water archaeology in western Lake Huron

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/74939/1/j.1095-9270.2002.tb01415.x.pd

The First Population II Stars Formed in Externally Enriched Mini-halos

We present a simulation of the formation of the earliest Population II stars, starting from cosmological initial conditions and ending when metals created in the first supernovae are incorporated into a collapsing gas-cloud. This occurs after a supernova blast-wave collides with a nearby mini-halo, inducing further turbulence that efficiently mixes metals into the dense gas in the center of the halo. The gas that first collapses has been enriched to a metallicity of Z ~ 2e-5 Zsun. Due to the extremely low metallicity, collapse proceeds similarly to metal-free gas until dust cooling becomes efficient at high densities, causing the cloud to fragment into a large number of low mass objects. This external enrichment mechanism provides a plausible origin for the most metal-poor stars observed, such as SMSS J031300.36-670839.3, that appear to have formed out of gas enriched by a single supernova. This mechanism operates on shorter timescales than the time for low-mass mini-halos (M < 5e5 Msun) to recover their gas after experiencing a supernova. As such, metal-enriched stars will likely form first via this channel if the conditions are right for it to occur. We identify a number of other externally enriched halos that may form stars in this manner. These halos have metallicities as high as 0.01 Zsun, suggesting that some members of the first generation of metal-enriched stars may be hiding in plain sight in current stellar surveys.Comment: Accepted for publication in MNRAS. Minor updates and one additional figure. Movies and images available at http://www.roe.ac.uk/~brs/pop2prim

Late Pop III Star Formation During the Epoch of Reionization: Results from the Renaissance Simulations

We present results on the formation of Pop III stars at redshift 7.6 from the Renaissance Simulations, a suite of extremely high-resolution and physics-rich radiation transport hydrodynamics cosmological adaptive-mesh refinement simulations of high redshift galaxy formation performed on the Blue Waters supercomputer. In a survey volume of about 220 comoving Mpc$^3$, we found 14 Pop III galaxies with recent star formation. The surprisingly late formation of Pop III stars is possible due to two factors: (i) the metal enrichment process is local and slow, leaving plenty of pristine gas to exist in the vast volume; and (ii) strong Lyman-Werner radiation from vigorous metal-enriched star formation in early galaxies suppresses Pop III formation in ("not so") small primordial halos with mass less than $\sim$ 3 $\times$ 10$^7$ M$_\odot$. We quantify the properties of these Pop III galaxies and their Pop III star formation environments. We look for analogues to the recently discovered luminous Ly $\alpha$ emitter CR7 (Sobral et al. 2015), which has been interpreted as a Pop III star cluster within or near a metal-enriched star forming galaxy. We find and discuss a system similar to this in some respects, however the Pop III star cluster is far less massive and luminous than CR7 is inferred to be.Comment: 8 pages, 4 figures, 3 tables. Accepted by Ap

Probing The Ultraviolet Luminosity Function of the Earliest Galaxies with the Renaissance Simulations

In this paper, we present the first results from the Renaissance Simulations, a suite of extremely high-resolution and physics-rich AMR calculations of high redshift galaxy formation performed on the Blue Waters supercomputer. These simulations contain hundreds of well-resolved galaxies at $z \sim 25-8$, and make several novel, testable predictions. Most critically, we show that the ultraviolet luminosity function of our simulated galaxies is consistent with observations of high-z galaxy populations at the bright end of the luminosity function (M$_{1600} \leq -17$), but at lower luminosities is essentially flat rather than rising steeply, as has been inferred by Schechter function fits to high-z observations, and has a clearly-defined lower limit in UV luminosity. This behavior of the luminosity function is due to two factors: (i) the strong dependence of the star formation rate on halo virial mass in our simulated galaxy population, with lower-mass halos having systematically lower star formation rates and thus lower UV luminosities; and (ii) the fact that halos with virial masses below $\simeq 2 \times 10^8$ M$_\odot$ do not universally contain stars, with the fraction of halos containing stars dropping to zero at $\simeq 7 \times 10^6$ M$_\odot$. Finally, we show that the brightest of our simulated galaxies may be visible to current and future ultra-deep space-based surveys, particularly if lensed regions are chosen for observation.Comment: 7 pages, 4 figures, accepted by The Astrophysical Journal Letter

Validating Semi-Analytic Models of High-Redshift Galaxy Formation using Radiation Hydrodynamical Simulations

We use a cosmological hydrodynamic simulation calculated with Enzo and the semi-analytic galaxy formation model (SAM) GAMMA to address the chemical evolution of dwarf galaxies in the early universe. The long-term goal of the project is to better understand the origin of metal-poor stars and the formation of dwarf galaxies and the Milky Way halo by cross-validating these theoretical approaches. We combine GAMMA with the merger tree of the most massive galaxy found in the hydrodynamic simulation and compare the star formation rate, the metallicity distribution function (MDF), and the age-metallicity relationship predicted by the two approaches. We found that the SAM can reproduce the global trends of the hydrodynamic simulation. However, there are degeneracies between the model parameters and more constraints (e.g., star formation efficiency, gas flows) need to be extracted from the simulation to isolate the correct semi-analytic solution. Stochastic processes such as bursty star formation histories and star formation triggered by supernova explosions cannot be reproduced by the current version of GAMMA. Non-uniform mixing in the galaxy's interstellar medium, coming primarily from self-enrichment by local supernovae, causes a broadening in the MDF that can be emulated in the SAM by convolving its predicted MDF with a Gaussian function having a standard deviation of ~0.2 dex. We found that the most massive galaxy in the simulation retains nearby 100% of its baryonic mass within its virial radius, which is in agreement with what is needed in GAMMA to reproduce the global trends of the simulation.Comment: 26 pages, 13 figures, 2 tables, submitted to ApJ (version 2